Difference between revisions of "Ilmenite Reduction"
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| − | ([[LUNOX]]) from lunar resources. The term "reduction" refers to a change in the oxidation state of an atom, molecule, or ion in which an electron is gained. This is the opposite of an oxidation reaction in which an electron is lost. | + | ([[LUNOX]]) from lunar resources. The term "reduction" refers to a change in the oxidation state of an atom, molecule, or ion in which an electron is gained. This is the opposite of an oxidation reaction in which an electron is lost. |
==Hydrogen Reduction== | ==Hydrogen Reduction== | ||
[[Hydrogen]] reduction is one method currently being tested by many Universities. Products of the hydrogen reduction are free [[iron]], [[rutile|titanium dioxide (TiO<sub>2</sub>)]], and [[water]]. The resulting water can be removed by condensation and separated via electrolysis to produce oxygen and H<SUB>2</SUB> (hydrogen). The hydrogen is then be recycled into the reaction. | [[Hydrogen]] reduction is one method currently being tested by many Universities. Products of the hydrogen reduction are free [[iron]], [[rutile|titanium dioxide (TiO<sub>2</sub>)]], and [[water]]. The resulting water can be removed by condensation and separated via electrolysis to produce oxygen and H<SUB>2</SUB> (hydrogen). The hydrogen is then be recycled into the reaction. | ||
Revision as of 18:43, 9 June 2008
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Reduction of ilmenite (FeTiO3) refers to a variety of chemical reactions proposed for use in the production of oxygen
(LUNOX) from lunar resources. The term "reduction" refers to a change in the oxidation state of an atom, molecule, or ion in which an electron is gained. This is the opposite of an oxidation reaction in which an electron is lost.
Hydrogen Reduction
Hydrogen reduction is one method currently being tested by many Universities. Products of the hydrogen reduction are free iron, titanium dioxide (TiO2), and water. The resulting water can be removed by condensation and separated via electrolysis to produce oxygen and H2 (hydrogen). The hydrogen is then be recycled into the reaction.
The basic process sequence is to separate ilmenite from lunar soil, crush it to a fine powder to maximize the surface area, heat the ilmenite in an enclosed reaction vessel in the presence of hydrogen gas, condense the steam which is produced by the reaction, and then use electrolysis to separate the water into hydrogen and oxygen. The process is best utilized if the plant is sited in a location in which ilmenite composes a high fraction of the soil.
The reaction sequence is:
Reduction:
FeTiO3+H2 ---->Fe+TiO2+H2O
Electrolysis:
2H2O ---->2 H2+ O2
Net Reaction:
2FeTiO3----> 2Fe+2TiO2+ O2
Carbothermal Reduction
Oxygen can be retrieved from Ilmenite (FeTiO3) and Rutile (TiO2) by means of carbothermal reduction. In experiments, powdered carbon and powdered ilmenite/rutile were evenly mixed and then heated to 1500 degrees Celsius. The end products of this reaction are Oxygen and a high strength Ceramic-metal composite (Cermet) of Iron (Fe) and Titanium Carbide (TiC) which has high chemical stability. The amount of reinforcing TiC ceramic in the matrix can be controlled via the amount of rutile and carbon used. While this method provides a means of retrieving all of the oxygen from ilmenite/rutile and a potential for producing reinforced, high performance and wear components and cutting tools from lunar regolith, it is at the cost of highly valuable carbon needed for biological processes. The process will also require the separation of ilmenite/rutile from regolith by some means.
Stoichiometry for this reaction:
Ilmenite:
FeTiO3 + 4C ---->Fe + TiC + 3CO
Ilmenite and Rutile:
FeTiO3 + nTiO2 + (4+3n)C ---->Fe + (1+n)TiC + (3+2n)CO
Where n represents the number of TiO2 molecules
Reduction with CO
This reaction is based on a fluidized bed scheme which is similar to large scale proposals for Hydrogen Reduction. The product of CO reduction of Ilmenite is Carbon Dioxide (CO2), which must be cracked using significant energy in an endothermic electrolysis reaction to yield oxygen, which can be drawn off via a ceramic membrane. See this paper, page 9. The presence of solar wind implanted carbon in the regolith (20-30ppm) will allow the recovery of additional carbon, but the presence of solar wind implanted hydrogen (hundreds of ppm) may complicate the reaction into one that involves methane (CH4). The CO reduction of ilmenite is slower than the H2 process, but by less than an order of magnitude for any given temperature.
The reaction sequence is:
Reduction:
FeTiO3 + CO ---->Fe + TiO2 + CO2
Endothermic cracking:
2CO2 ----> 2CO + O2
Net Reaction:
2FeTiO3 + 2CO ---->2Fe + 2TiO2 + 2CO + O2
Methane Reduction
| Please note: Methane Reduction This section is a placeholder for work currently in progress. |
Li or Na Reduction
Plasma Reduction
External Links
- ISRU on the Moon. by Larry Taylor http://www.lpi.usra.edu/lunar_knowledge/LTaylor.pdf
- Extraction Techniques-Oxygen. G. L. Kulcinski, February 18, 2004 http://fti.neep.wisc.edu/neep533/SPRING2004/lecture13.pdf
- Processing Lunar Soils for Oxygen and Other Materials. Knudsen & Gibson http://nss.org/settlement/nasa/spaceresvol3/plsoom1.htm
- Lunar Oxygen Production - A Maturing Technology
- The Effect of TiO2 on Synthesizing Fe-TiC Composites
- Resources of Near-Earth Space. Univ. of Arizona Press
